Phase Analysis of Alkali-Activated Slag Hybridized with Low-Calcium and High-Calcium Fly Ash
نویسندگان
چکیده
This paper investigates the hydrated phase assemblage, microstructure, and gel composition of sodium hydroxide (NaOH)-activated fly ash–slag blends with either low-calcium or high-calcium ash. The results show that nature precipitated calcium–aluminosilicate–hydrate (C-A-S-H) alkali aluminosilicate-hydrate (N-A-S-H) depends on ash slag-to-fly ratio. However, regardless ratio, a universal linear compositional relationship exists between Al/Ca ratio Si/Ca in gels. indicates there structural limitation incorporation Al3+ for Si4+ tetrahedral silicate C-A-S-H, N-A-S-H, metastable N-C-A-S-H In hybrid slag–fly system, framework structure gels is an assemblage aluminosilicate units heterogeneous Ca2+ Na+ distribution. amount reactivity calcium alkalis seem to play critical role determining properties systems. low cementitious capability alkali-activated may be attributed unstable concurrent high Na Ca contents.
منابع مشابه
Properties of alkali activated slag-fly ash blends with limestone addition
• A submitted manuscript is the author's version of the article upon submission and before peer-review. There can be important differences between the submitted version and the official published version of record. People interested in the research are advised to contact the author for the final version of the publication, or visit the DOI to the publisher's website. • The final author version ...
متن کاملALKALI Activated FLY-ASH Based Geopolymer Concrete
Considering the increasing demand for developing alternative construction materials, due to the growing environmental concerns, this paper discusses the feasibility of alkali activated geo-polymer concrete, as a future construction material. The main objective of this study involves observation of structural behaviours of the fresh fly ash-based geo-polymer concrete, understanding the basic mix...
متن کاملThe Characterization of Fixation of Ba, Pb, and Cu in Alkali-Activated Fly Ash/Blast Furnace Slag Matrix
The fixation of heavy metals (Ba, Cu, Pb) in an alkali-activated matrix was investigated. The matrix consisted of fly ash and blast furnace slag (BFS). The mixture of NaOH and Na-silicate was used as alkaline activator. Three analytical techniques were used to describe the fixation of heavy metals-X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) equipped with energy di...
متن کاملMicrostructural Characteristics of Geopolymers Based on Alkali-Activated Fly Ash
Aluminosilicate geopolymers with a high silica molar ratio have been prepared by mixing Croatian coal-ash (ASTM Class F) and sodium silicate solution (water glass, technical grade). The samples were cured at 85 °C for 8 h and 24 h in different experimental conditions. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM/EDS) have been use...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Sustainability
سال: 2022
ISSN: ['2071-1050']
DOI: https://doi.org/10.3390/su14073767